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Advances in the slurry reactor technology of the anthraquinone process for H

Hongbo Li, Bo Zheng, Zhiyong Pan, Baoning Zong, Minghua Qiao

《化学科学与工程前沿（英文）》 2018年第12卷第1期页码 124-131 doi: 10.1007/s11705-017-1676-5

摘要： This paper overviews the development of the anthraquinone auto-oxidation (AO) process for the production of hydrogen peroxide in China and abroad. The characteristics and differences between the fixed-bed and fluidized-bed reactors for the AO process are presented. The detailed comparison indicates that the production of hydrogen peroxide with the fluidized-bed reactor has many advantages, such as lower operation cost and catalyst consumption, less anthraquinone degradation, higher catalyst utilization efficiency, and higher hydrogenation efficiency. The key characters of the production technology of hydrogen peroxide based on the fluidized-bed reactor developed by the Research Institute of Petroleum Processing, Sinopec are also disclosed. It is apparent that substituting the fluidized-bed reactor for the fixed-bed reactor is a major direction of breakthrough for the production technology of hydrogen peroxide in China.

关键词： anthraquinone process fixed-bed reactor slurry-bed reactor hydrogen peroxide

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Concept and application of anaerobic suspended granular sludge bed (SGSB) reactor for wastewater treatment

Mingxia ZHENG,Zhong YAN,Jiane ZUO,Kaijun WANG

《环境科学与工程前沿（英文）》 2014年第8卷第5期页码 797-804 doi: 10.1007/s11783-013-0597-x

摘要： Bed expansion serves an important function in the design and operation of an upflow anaerobic reactor. An analysis of the flow pattern of expanded granular sludge bed (EGSB) reactors shows that most EGSB reactors do not behave as expanded bed reactors, as is widely perceived. Rather, these reactors behave as fluidized bed reactors based on the classic chemical reactor theory. In this paper, four bed expansion modes, divided as static bed, expanded bed, suspended bed, and fluidized bed, for bioreactors are proposed. A high-rate anaerobic suspended granular sludge bed (SGSB) reactor was then developed. The SGSB reactor is an upflow anaerobic reactor, and its expansion degree can be easily controlled within a range to maintain the suspended status of the sludge bed by controlling upflow velocity. The results of the full-scale reactor confirmed that the use of SGSB reactors is advantageous. The full-scale SGSB reactor runs stably and achieves high COD removal efficiency (about 90%) at high loading rates (average 40 kg-COD·m ·d , maximum to 52 kg-COD·m ·d ) based on the SGSB theory, and its expansion degree is between 22% and 37%.

关键词： expansion characteristic high-rate bioreactor anaerobic suspended granular sludge bed expanded granular sludge bed reactor

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Kinetic study of hydrodesulfurization of coker gas oil in a slurry reactor

Haiding XIANG, Tiefeng WANG

《化学科学与工程前沿（英文）》 2013年第7卷第2期页码 139-144 doi: 10.1007/s11705-013-1323-8

摘要： Coker gas oil (CGO) is a poor-quality feedstock for fluidized bed catalytic cracking (FCC) or hydrocracking. The pretreatment of CGO, especially hydrotreating, can significantly improve the product quality and protect the catalyst. In this work, we studied the hydrodesulfurization (HDS) of CGO in a slurry reactor. All the experiments were carried out in an autoclave using a NiMo/Al O catalyst at reaction temperature 340°C–400°C, pressure 6–10 MPa, and stirring speed 800 r·min , with hydrogen-to-oil ratio in the range of 500–1500. The effects of the operating parameters on the desulfurization ratio were investigated and discussed. A macro reaction kinetic model was established for the HDS of CGO in the slurry reactor.

关键词： coker gas oil hydrodesulfurization slurry reactor reaction kinetic model

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Study on direct alcohol/ether fuel synthesis process in bubble column slurry reactor

Zhen CHEN, Haitao ZHANG, Weiyong YING, Dingye FANG

《化学科学与工程前沿（英文）》 2010年第4卷第4期页码 461-471 doi: 10.1007/s11705-010-0517-6

摘要： The recent studies of direct alcohol/ether synthesis process in slurry reactors were reviewed, and the research work in our laboratory was carried out in this paper. a global kinetics model for direct dimethyl ether (DME) synthesis from syngas over a novel Cu-Zn-Al-Zr slurry catalyst was established according to the total of 25 experimental data, and a steady-state one-dimensional mathematical model was further developed in bubble column slurry reactor (BCSR), which was assumed that the bubble phase was plug flow, and the liquid phase was fully mixed flow. The numerical simulations of reactor design of 100000 t/a dimethyl ether pilot plant indicate that higher pressure and lower temperature were favorable to the increase of CO conversion, selectivity of dimethyl ether, product yield and height of slurry bed. The optimal operating conditions for DME synthesis process were obtained: reaction temperature at 240°C, reactor pressure at 5 MPa and reactor diameter of 2.5 m.

关键词： syngas alcohol/ether fuel slurry catalyst bubble column slurry reactor global kinetics mathematical model

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Circulating fluidized bed biological reactor for nutrients removal

CUI Yubo, LIU Hongbo, BAI Chunxue

《环境科学与工程前沿（英文）》 2008年第2卷第3期页码 349-353 doi: 10.1007/s11783-008-0051-7

摘要： A new biological nitrogen removal process, which is named herein “The circulating fluidized bed bioreactor (CFBBR)”, was developed for simultaneous removal of nitrogen and organic matter. This process was composed of an anaerobic bed (Riser), aerobic bed (Downer) and connecting device. Influent and nitrified liquid from the aerobic bed enters the anaerobic bed from the bottom of the anaerobic bed, completing the removal of nitrogen and organic matter. The system performance under the conditions of different inflow loadings and nitrified liquid recirculation rates ranging from 200% to 600% was examined. From a technical and economic point of view, the optimum nitrified liquid recirculation rate was 400%. With a shortest total retention time of 2.5 h (0.8 h in the anaerobic bed and 1.5 h in the aerobic bed) and a nitrified liquid recirculation rate of 400% based on the influent flow rate, the average removal efficiencies of total nitrogen (TN) and soluble chemical oxygen demand (SCOD) were found to be 88% and 95%, respectively. The average effluent concentrations of TN and SCOD were 3.5 mg/L and 16 mg/L, respectively. The volatile suspended solid (VSS) concentration, nitrification rate and denitrification rate in the system were less than 1.0 g/L, 0.026–0.1 g NH-N/g VSSd, and 0.016–0.074 g NO-N/g VSSd, respectively.

关键词： soluble chemical bioreactor biological nitrogen optimum nitrified nitrogen removal

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Application of gamma-ray attenuation technology in density measurement of a slurry reactor

Jian XU, Weisheng WEI, Kai ZHANG

《化学科学与工程前沿（英文）》 2010年第4卷第4期页码 486-490 doi: 10.1007/s11705-010-0509-6

摘要： Axial density profile of the gas-liquid-solid mixture in a slurry bubble column was measured by gamma-ray attenuation technology. Several measures for improving measurement precision were presented based on the discussion on attenuation law. It was found that the response frequency and the ray intensity should be as high as possible to improve the measurement precision. The mass absorption coefficient depended on not the object’s thickness but the location where the object was placed between the ray source and the detector. The results showed that the density in the column decreases with the increase of column height, which indicates that the measurement by gamma-ray attenuation is reasonable.

关键词： slurry reactor axial density distribution gamma-ray attenuation technology

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Large-scale industrial manufacturing of carbon nanotubes in a continuous inclined mobile-bed rotatingreactor via the catalytic chemical vapor deposition process

Sophie L. Pirard, Sigrid Douven, Jean-Paul Pirard

《化学科学与工程前沿（英文）》 2017年第11卷第2期页码 280-289 doi: 10.1007/s11705-017-1635-1

摘要： This article reports the different steps of the design, development and validation of a process for continuous production of carbon nanotubes (CNTs) via catalytic chemical vapor deposition from the laboratory scale to the industrial production. This process is based on a continuous inclined mobile-bed rotating reactor and very active catalysts using methane or ethylene as carbon source. The importance of modeling taking into account the hydrodynamic, physicochemical and physical phenomena that occur during CNT production in the process analysis is emphasized. The impact of this invention on the environment and human health is taken into consideration too.

关键词： carbon nanotubes catalytic chemical vapor deposition inclined rotating reactor industrial process scaling-up

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direct electro-Fenton process and bioremediation for the treatment of pyrene-contaminated soil in a slurryreactor

Wendi XU,Shuhai GUO,Gang LI,Fengmei LI,Bo WU,Xinhong GAN

《环境科学与工程前沿（英文）》 2015年第9卷第6期页码 1096-1107 doi: 10.1007/s11783-015-0804-z

摘要： A combined treatment technology (DEF-BIO) using the direct electro-Fenton (DEF) process and bioremediation (BIO) was established in this study. The performance of the DEF-BIO process on the remediation of a pyrene (PYR)-contaminated soil was evaluated in a slurry reactor. The appropriate order of application was to conduct the DEF process followed by BIO, evaluated through analysis of the degradation characteristics of each process individually. In addition, the application time of the DEF process affected the efficiency of the combined process. The optimum time to apply the DEF process was determined through an analysis of the induced changes in PYR intermediates, pH, soil organic matter (SOM) and bacteria. The optimum application time of the DEF process was 6 h. All the induced changes were beneficial for the BIO phase. The removal of PYR was 91.02% for DEF–BIO after 72 h, and the efficiency was almost 50% increased, compared with the individual DEF and BIO treatments. Therefore, the combined process of DEF–BIO process may be an efficient and promising method for the remediation.

关键词： direct electro-Fenton bioremediation slurry reactor combined process pyrene

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Effects of carrier-attached biofilm on oxygen transfer efficiency in a moving bed biofilm reactor

Yanling WEI,Xunfei YIN,Lu QI,Hongchen WANG,Yiwei GONG,Yaqian LUO

《环境科学与工程前沿（英文）》 2016年第10卷第3期页码 569-577 doi: 10.1007/s11783-015-0822-x

摘要： Three laboratory-scale moving bed biofilm reactors (MBBR) with different carrier filling ratios ranging from 40% to 60% were used to study the effects of carrier-attached biofilm on oxygen transfer efficiency. In this study, we evaluated the performance of three MBBRs in degrading chemical oxygen demand and ammonia. The three reactors removed more than 95% of -N at an air flow-rate of 60 L·h . The standard oxygen transfer efficiency (αSOTE) of the three reactors was also investigated at air flow-rates ranging from 60 to 100 L·h . These results were compared to αSOTE of wastewater with a clean carrier (no biofilm attached). Results showed that under these process conditions, αSOTE decreased by approximately 70% as compared to αSOTE of wastewater at a different carrier-filling ratio. This indicated that the biofilm attached to the carrier had a negative effect on αSOTE. Mechanism analysis showed that the main inhibiting effects were related to biofilm flocculants and soluble microbial product (SMP). Biofilm flocs could decrease αSOTE by about 20%, and SMP could decrease αSOTE by 30%–50%.

关键词： carrier biofilm oxygen transfer efficiency moving bed biofilm reactor

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Effect of nitrobenzene on the performance and bacterial community in an expanded granular sludge bedreactor treating high-sulfate organic wastewater

Jun Li, Wentao Li, Gan Luo, Yan Li, Aimin Li

《环境科学与工程前沿（英文）》 2019年第13卷第1期 doi: 10.1007/s11783-019-1090-y

摘要：

Less than 50 mg/L nitrobenzene brought little effect on anaerobic sulfate reduction.

Kinetics of sulfate reduction under different nitrobenzene contents was studied.

Increased nitrobenzene contents greatly changed the bacterial community structure.

Genus Desulfovibrio played the key role in anaerobic sulfate reduction process.

关键词： Nitrobenzene (NB) Sulfate-reducing bacteria (SRB) Bacterial community Sulfate reduction High-throughput sequencing

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Experimental study on slurry-induced fracturing during shield tunneling

Teng WANG, Dajun YUAN, Dalong JIN, Xinggao LI

《结构与土木工程前沿（英文）》 2021年第15卷第2期页码 333-345 doi: 10.1007/s11709-021-0718-8

摘要： Facial support in slurry shield tunneling is provided by slurry pressure to balance the external earth and water pressure. Hydraulic fracturing may occur and cause a significant decrease in the support pressure if the slurry pressure exceeds the threshold of the soil or rock material, resulting in a serious face collapse accident. Preventing the occurrence of hydraulic fracturing in a slurry shield requires investigating the effects of related influencing factors on the hydraulic fracturing pressure and fracture pattern. In this study, a hydraulic fracturing apparatus was developed to test the slurry-induced fracturing of cohesive soil. The effects of different sample parameters and loading conditions, including types of holes, unconfined compressive strength, slurry viscosity, and axial and circumferential loads, on the fracturing pressure and fracture dip were examined. The results indicate that the fracture dip is mainly affected by the deviator stress. The fracturing pressure increases linearly with the increase in the circumferential pressure, but it is almost independent of the axial pressure. The unconfined compressive strength of soil can reflect its ability to resist fracturing failure. The fracturing pressure increases with an increase in the unconfined compressive strength as well as the slurry viscosity. Based on the test results, an empirical approach was proposed to estimate the fracturing pressure of the soil.

关键词： slurry shield tunneling hydraulic fracturing test fracturing pressure fracture dip unconfined compressive strength slurry viscosity

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山东石岛湾200 MW_e 球床模块式高温气冷堆(HTR-PM) 核电站示范工程 Review

张作义, 董玉杰, 李富, 张征明, 王海涛, 黄晓津, 李红, 刘兵, 吴莘馨, 王宏, 刁兴中, 张海泉, 王金华

《工程（英文）》 2016年第2卷第1期页码 112-118 doi: 10.1016/J.ENG.2016.01.020

摘要：

世界首台球床模块式高温气冷堆(HTR-PM) 核电站示范工程于2012 年12 月9日在中国山东省荣成市石岛湾厂区完成第一罐混凝土的浇筑，2015年6月完成反应堆厂房建设，然后进入设备安装阶段。目前正在向着在2017年年底实现并网发电的目标顺利推进。1个HTR-PM反应堆模块的热功率是250 MWth，反应堆堆芯氦气的进出口温度分别是250 °C 和750 °C。蒸汽发生器出口的蒸汽参数是13.25 MPa/567 °C。2个球床反应堆模块连接1台蒸汽轮机，形成一座210 MWe的核电站。项目团队克服了巨大困难，利用中国现有的工业制造技术研制出世界首台设备，实现了一系列重大技术创新。在研发的规划和实施、工业合作伙伴关系的建立、主设备制造、燃料生产、安全审查、站址选择以及安全性和经济性的平衡等方面取得了令人欣慰的进展，为世界同行积累了可以借鉴的经验。

关键词：核能高温气冷堆球床模块式高温气冷堆球床模块式高温气冷堆

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气升式浆态床反应器的过程强化 Review

耿淑君, 毛在砂, 黄青山, 杨超

《工程（英文）》 2021年第7卷第3期页码 304-325 doi: 10.1016/j.eng.2021.03.002

摘要：

气升式浆态床反应器是一种重要的气-液-固多相反应器，包括鼓泡塔反应器和环流反应器。这些反应器具有剪切应力低、混合程度好、传质/传热能力强、成本低等优点，已被广泛应用于许多工业过程，尤其是生物发酵和能源化工领域。为了进一步提高浆态床反应器的性能（即混合和传质/传热性能）和满足工业应用要求（如温度控制、减少返混和产品分离等），浆态床反应器的过程强化至关重要。首先，本文回顾了这两种反应器在强化混合和传质/传热方面的最新研究进展。然后，总结了浆态床反应器在连续生产时混合与分离的过程强化方法，其中，由于具有高效率和低成本的优点，推荐采用将环流反应器内的定向流动与水力旋流器的简单固-液分离相结合的过程强化技术。接着，系统地讨论了浆态床反应器所面临的问题和挑战，包括流型判别、气体分布器设计、固体颗粒影响及其他问题。本文还介绍了应用计算流体力学对浆态床反应器进行数值模拟的研究进展，讨论了建模的难点。最后，对工业浆态床反应器的设计进行总结和展望。

关键词：浆态床反应器气升式搅拌鼓泡塔环流反应器过程强化固体颗粒

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Abatement of mixed volatile organic compounds in a catalytic hybrid surface/packed-bed discharge plasmareactor

Lianjie Guo, Nan Jiang, Jie Li, Kefeng Shang, Na Lu, Yan Wu

《环境科学与工程前沿（英文）》 2018年第12卷第2期 doi: 10.1007/s11783-018-1017-z

摘要： In this study, post plasma-catalysis degradation of mixed volatile organic compounds (benzene, toluene, and xylene) has been performed in a hybrid surface/packed-bed discharge plasma reactor with Ag-Ce/ g-Al O catalyst at room temperature. The effect of relative air humidity on mixed VOCs degradation has also been investigated in both plasma-only and PPC systems. In comparison to the plasma-only system, a significant improvement can be observed in the degradation performance of mixed VOCs in PPC system with Ag-Ce/ g-Al O catalyst. In PPC system, 68% benzene, 89% toluene, and 94% xylene were degraded at 800 J·L , respectively, which were 25%, 11%, and 9% higher than those in plasma-only system. This result can be attributed to the high catalytic activity of Ag-Ce/ g-Al O catalyst to effectively decompose O and lead to generating more reactive species which are capable of destructing the VOCs molecules completely. Moreover, the presence of Ag-Ce/ g-Al O catalyst in plasma significantly decreased the emission of discharge byproducts (NO and O ) and promoted the mineralization of mixed VOCs towards CO . Adding a small amount of water vapor into PPC system enhanced the degradation efficiencies of mixed VOCs, however, further increasing water vapor had a negative impact on the degradation efficiencies, which was primarily attributed to the quenching of energetic electrons by water vapor in plasma and the competitive adsorption of water vapor on the catalyst surface. Meanwhile, the catalysts before and after discharge were characterized by the Brunauer-Emment-Teller and X-ray photoelectron spectroscopy.

关键词： Mixed VOCs HSPBD plasma reactor Degradation Catalyst Relative humidity

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of an H reduction and moderate oxidation method for 3,5-dimethylpyridine hydrogenation in trickle bedreactor

《化学科学与工程前沿（英文）》 2022年第16卷第12期页码 1807-1817 doi: 10.1007/s11705-022-2243-2

摘要： The Ru/C catalyst prepared by impregnation method was used for hydrogenation of 3,5-dimethylpyridine in a trickle bed reactor. Under the same reduction conditions (300 °C in H₂), the catalytic activity of the non-in-situ reduced Ru/C-n catalyst was higher than that of the in-situ reduced Ru/C-y catalyst. Therefore, an in-situ H₂ reduction and moderate oxidation method was developed to increase the catalyst activity. Moreover, the influence of oxidation temperature on the developed method was investigated. The catalysts were characterized by Brunauer–Emmett–Teller method, hydrogen temperature programmed reduction H₂-TPR, hydrogen temperature-programmed dispersion (H₂-TPD), X-ray diffraction, energy dispersive spectroscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, O₂ chemisorption and oxygen temperature-programmed dispersion (O₂-TPD) analyses. The results showed that there existed an optimal Ru/RuO_x ratio for the catalyst, and the highest 3,5-dimethylpyridine conversion was obtained for the Ru/C-i1 catalyst prepared by in-situ H₂ reduction and moderate oxidation (oxidized at 100 °C). Excessive oxidation (200 °C) resulted in a significant decrease in the Ru/RuO_x ratio of the in-situ H₂ reduction and moderate oxidized Ru/C-i2 catalyst, the interaction between RuO_x species and the support changed, and the hard-to-reduce RuO_x species was formed, leading to a significant decrease in catalyst activity. The developed in-situ H₂ reduction and moderate oxidation method eliminated the step of the non-in-situ reduction of catalyst outside the trickle bed reactor.

关键词： Ru/C catalyst in-situ H₂ reduction and moderate oxidation in-situ reduction non-in-situ reduction hydrogenation of 3 5-dimethylpyridine

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标题作者时间类型操作

Advances in the slurry reactor technology of the anthraquinone process for H

Hongbo Li, Bo Zheng, Zhiyong Pan, Baoning Zong, Minghua Qiao

期刊论文

Concept and application of anaerobic suspended granular sludge bed (SGSB) reactor for wastewater treatment

Mingxia ZHENG,Zhong YAN,Jiane ZUO,Kaijun WANG

期刊论文

Kinetic study of hydrodesulfurization of coker gas oil in a slurry reactor

Haiding XIANG, Tiefeng WANG

期刊论文

Study on direct alcohol/ether fuel synthesis process in bubble column slurry reactor

Zhen CHEN, Haitao ZHANG, Weiyong YING, Dingye FANG

期刊论文

Circulating fluidized bed biological reactor for nutrients removal

CUI Yubo, LIU Hongbo, BAI Chunxue

期刊论文

Application of gamma-ray attenuation technology in density measurement of a slurry reactor

Jian XU, Weisheng WEI, Kai ZHANG

期刊论文

Large-scale industrial manufacturing of carbon nanotubes in a continuous inclined mobile-bed rotatingreactor via the catalytic chemical vapor deposition process

Sophie L. Pirard, Sigrid Douven, Jean-Paul Pirard

期刊论文

direct electro-Fenton process and bioremediation for the treatment of pyrene-contaminated soil in a slurryreactor

Wendi XU,Shuhai GUO,Gang LI,Fengmei LI,Bo WU,Xinhong GAN

期刊论文

Effects of carrier-attached biofilm on oxygen transfer efficiency in a moving bed biofilm reactor

Yanling WEI,Xunfei YIN,Lu QI,Hongchen WANG,Yiwei GONG,Yaqian LUO

期刊论文

Effect of nitrobenzene on the performance and bacterial community in an expanded granular sludge bedreactor treating high-sulfate organic wastewater

Jun Li, Wentao Li, Gan Luo, Yan Li, Aimin Li

期刊论文

Experimental study on slurry-induced fracturing during shield tunneling